Biosynthesis of methyl-proline containing griselimycins, natural products with anti-tuberculosis activity† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02622f Click here for additional data file.

Synthesis of ramariolide natural products and discovery of their targets in mycobacteria† †Electronic supplementary information (ESI) available. CCDC 1508942 and 1508943. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc08365j Click here for additional data file. Click here for additional data file.

Ramariolides A-D are natural products with antibacterial activity. To exploit their cellular mechanism, we here devise the first total synthesis and prepare a photoprobe for target identification. Antibacterial testing against several pathogenic strains including Mycobacterium tuberculosis revealed the highest potency for ramariolide A. Chemical proteomics unraveled binding to essential protein...

Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes† †Electronic supplementary information (ESI) available. CCDC 1517472 and 1517578. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01254c Click here for additional data file. Click here for additional data file.

State Key Laboratory of Organometallic Bio-Organic and Natural Products Chem Chemistry, Chinese Academy of Sciences, China. E-mail: [email protected]; kdin Department of Chemistry, South Universi Shenzhen 518055, China. E-mail: oscarchun University of Chinese Academy of Sciences, Collaborative Innovation Center of Chem 300071, China † Electronic supplementary information 1517578. For ESI an...

Transformable H-bonds and conformation in compressed glucose† †Electronic supplementary information (ESI) available: Detailed experimental data; detailed structural data. CCDC 1033994–1034008. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03588g Click here for additional data file. Click here for additional data file. Click here for additional data file. Click here for additional data file.

Alkene hydrogenation activity of enoate reductases for an environmentally benign biosynthesis of adipic acid† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02842j Click here for additional data file.

Photoinduced single-crystal-to-single-crystal phase transition and photosalient effect of a gold(i) isocyanide complex with shortening of intermolecular aurophilic bonds† †Electronic supplementary information (ESI) available: X-ray crystallographic data, optical properties, DFT calculations, and other additional information. CCDC [987280 and 987281]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02676d Click here for additional data file. Click here for additional data file. Click here for additional data file. Click here for additional data file. Click here for additional data file.